Concepts of stability and symmetry in irreversible thermodynamics are developed through the analysis of system energy flows. The excess power function, derived from a local energy conservation equation, is shown to yield necessary and sufficient stability criteria for linear and nonlinear irreversible processes. In the absence of symmetry-destroying external forces, the linear range may be characterized by a set of phenomenological coefficient symmetries relating coupled forces and displacements, velocities, and accelerations, whereas rotational phenomena in nonlinear processes may be characterized by (...) skew-symmetric components of the phenomenological coefficients. A physical interpretation of the nature of the skew-symmetric parts is given and the variational principle of minimum dissipation of energy is related to a stability criterion. (shrink)

The scope of the thermodynamic theory of nonlinear irreversible processes is widened to include the nonlinear stability analysis of system motion. The emphasis is shifted from the analysis of instantaneous energy flows to that of the average work performed by periodic nonlinear processes. The principle of virtual work separates dissipative and conservative forces. The vanishing of the work of conservative forces determines the natural period of oscillation. Stability is then determined by the variations of the dissipative forces with amplitude of (...) oscillation. If the work is a minimum, under certain conditions, the motion is stable. Reduction to linear analysis shows the coincidence with the impedance analysis of electrical circuit theory. The theory is applied to the analysis of temporal interactions of nonlinear irreversible processes in the particular cases of synchronization and hysteresis. Characteristic nonequilibrium phenomena of directional energy transfers, self-excitation, system passivity, wave modulation, and “beat” phenomena are observed. Possible relationships with biological processes are discussed. (shrink)

The generalized thermodynamic potential analysis of nonlinear irreversible processes precludes the analysis of rotational processes. The nonexistence of scalar potential functions necessitates a thermodynamic analysis of the system forces. A field analysis in the phase space of the generalized displacements and velocities treats the force components as tensors of second order that tend to deform and rotate the irreversible process, which is viewed as an elastic material. The analysis of chemical oscillatory processes involves the introduction of the thermodynamic vector potential, (...) which is subsequently used in the formulation of a variational principle and to define an energy flux vector. The direction of energy flow elucidates the mechanism by which steady motion is maintained and it is a characteristic property of open systems. Field analyses of systems that are described by half and single degrees of freedom are contrasted. (shrink)

A simple random walk model has been shown by Gaveauet al. to give rise to the Klein-Gordon equation under analytic continuation. This absolutely most probable path implies that the components of the Dirac wave function have a common phase; the influence of spin on the motion is neglected. There is a nonclassical path of relative maximum likelihood which satisfies the constraint that the probability density coincide with the quantum mechanical definition. In three space dimensions, and in the presence of electromagnetic (...) interaction, the Lagrangian for this optimal, nonclassical path coincides with the Lagrangian of the Dirac particle. The nonrelativistic, or diffusion, limit is shown to be a formal consequence of Einstein's dynamical equilibrium condition; the continuity equation reduces to the same diffusion equation derived from Schrödinger's equation. The relativistic, massless limit, which would describe a neutrino, is comparable (in the sense of analytic continuation) to a nonviscous liquid whose molecules possess internal degrees of freedom. (shrink)

It is shown that: (i) the Onsager-Machlup postulate applies to nonlinear stochastic processes over a time scale that, while being much longer than the correlation times of the random forces, is still much shorter than the time it takes for the nonlinear distortion to become visible; (ii) these are also the conditions for the validity of the generalized Fokker-Planck equation; and (iii) when the fine details of the space-time structure of the stochastic processes are unimportant, the generalized Fokker-Planck equation can (...) be replaced by the ordinary Fokker-Planck equation. (shrink)

The thermodynamics of averaged motion treats the asymptotic spatiotemporal evolution of nonlinear irreversible processes. Dissipative and conservative actions are associated with short and long spatiotemporal scales, respectively. The motion of asymptotically stable systems is slow, monotonic, and continuous, so that the microscopic state variable description of rapid motion can be supplanted by an analysis of the macroscopic variable equations of motion of amplitude and phase. Rapid motion is associated with instability, and the direction of system motion is determined by thermodynamic (...) criteria, in place of an analysis of the microscopic equations of motion. The characteristic structural configurations, deduced from the extremum principles of partial differential equations, are compared with the thermodynamic criteria. As a result of the nature of asymptotic motion, variational principles exist which characterize the asymptotic states of the system. (shrink)

Nonrelativistic quantum mechanics can be derived from real Markov diffusion processes by extending the concept of probability measure to the complex domain. This appears as the only natural way of introducing formally classical probabilistic concepts into quantum mechanics. To every quantum state there is a corresponding complex Fokker-Planck equation. The particle drift is conditioned by an auxiliary equation which is obtained through stochastic energy conservation; the logarithmic transform of this equation is the Schrödinger equation. To every quantum mechanical operator there (...) is a stochastic process; the replacement of operators by processes leads to all the well-known results of quantum mechanics, using stochastic calculus instead of formal quantum rules. Comparison is made with the classical stochastic approaches and the Feynman path integral formulation. (shrink)